Amidoboronates: bringing together the synthesis of BN-heterocycles via a reductive coupling and dynamic covalent chemistry
Dalton Transactions Pub Date: 2023-06-20 DOI: 10.1039/D3DT01863F
Abstract
This Perspective describes how amidoboronates open up new chemical space spanning the areas of BN-heterocycles and dynamic covalent chemistry. BN-containing heterocycles offer the potential to access new properties and reactivity compared to their C–C analogues. Amidoboronates are introduced as a new class of B–N heterocycles that can be synthesised in three isomeric forms (meso5, rac5 and rac6) from the reductive coupling of N-aryl iminoboronates. Furthermore, initial investigations on the dynamic covalent chemistry of amidoboronates are discussed, such as the reversibility of C–C bond formation following the reductive coupling and tuning the rac5/rac6 ratio via dynamic covalent B–N and B–O bonds.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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