Hydrophosphorylation of electron-deficient alkenes and alkynes mediated by convergent paired electrolysis?
Chemical Communications Pub Date: 2022-06-27 DOI: 10.1039/D2CC02745C
Abstract
A straightforward and practical strategy for hydrophosphorylation of electron-deficient alkenes and alkynes to access γ-ketophosphine oxides, enabled by a convergent paired electrolysis (CPE) in the absence of a metal, base, and redox reagent, has been described. Mechanistic studies have revealed that the diarylphosphane oxides play the dual role of a phosphorus radical precursor and hydrogen donor in this transformation.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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