New approaches to the functionalization of the 1-carba-closo-decaborate anion??

Chemical Communications Pub Date: 2022-02-18 DOI: 10.1039/D1CC06395B

Abstract

Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]? at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.

Graphical abstract: New approaches to the functionalization of the 1-carba-closo-decaborate anion
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