Diverse reactivity of a magnesium silanide toward ketones?
Chemical Communications Pub Date: 2022-08-30 DOI: 10.1039/D2CC03966D
Abstract
The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing reagent.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4