Nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl bromides by convergent paired electrolysis?
Chemical Communications Pub Date: 2022-06-23 DOI: 10.1039/D2CC02641D
Abstract
Herein, nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl bromides by convergent paired electrolysis was developed in an undivided cell. This protocol features good functional group tolerance, and is chemical redox agent- and sacrificial electrode-free. Mechanistic studies indicated that the base was crucial for the decarboxylation step and a NiI/NiIII catalytic cycle was involved in this transformation.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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