Electric-field-induced coupling of aryl iodides with a nickel(0) complex?
Chemical Communications Pub Date: 2022-10-10 DOI: 10.1039/D2CC03671A
Abstract
The formation of carbon–carbon bonds with transition metal reagents serves as a cornerstone of organic synthesis. Here, we show that the reactivity of an otherwise kinetically inert transition metal complex can be induced by an external electric field to affect a coupling reaction. These results highlight the importance of electric field effects in reaction chemistry and offers a new strategy to modulate organometallic reactivity.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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