De novo asymmetric Achmatowicz approach to oligosaccharide natural products
Chemical Communications Pub Date: 2022-10-28 DOI: 10.1039/D2CC05280F
Abstract
The development and application of the asymmetric synthesis of oligosaccharides from achiral starting materials is reviewed. This de novo asymmetric approach centers around the use of asymmetric catalysis for the synthesis of optically pure furan alcohols in conjunction with Achmatowicz oxidative rearrangement for the synthesis of various pyranones. In addition, the use of a diastereoselective palladium-catalyzed glycosylation and subsequent diastereoselective post-glycosylation transformation was used for the synthesis of oligosaccharides. The application of this approach to oligosaccharide synthesis is discussed.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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