Phosphine-based metal–organic layers to construct single-site heterogeneous catalysts for arene borylation?
Chemical Communications Pub Date: 2023-06-02 DOI: 10.1039/D3CC01858J
Abstract
Metal–organic layers (MOLs) are versatile platforms for creating single-site heterogeneous catalysts. Incorporating molecular functionalities into MOLs is crucial for catalysis. In this study, we synthesized phosphine-containing MOLs constructed from Hf6-oxo secondary building units (SBUs) and phosphine ligands. The mono(phosphine)-Ir complexes generated by the metalation of TPP-MOL were highly active as heterogeneous catalysts for the C(sp2)–H borylation of a range of arenes. This research expands the diversity of MOL-based catalysts.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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