Oxygen vacancy regulated selective hydrogenation of α,β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts?

Catalysis Science & Technology Pub Date: 2022-08-22 DOI: 10.1039/D2CY01298G

Abstract

Selective hydrogenation of α,β-unsaturated aldehydes under mild conditions is a great challenge in the synthesis of the corresponding alcohols. Herein, we report that a series of oxygen vacancy enriched MgAl-LDH coordinated transition metal hydroxide M(OH)x (M = Ru, Pt, Pd, Ag, Rh, Fe, Co, Ni and Cu) photocatalysts were successfully prepared taking advantage of the “memory effect” of MgAl-LDH. A high yield of α,β-unsaturated alcohols was achieved under visible light irradiation. DFT simulations and DRIFTS results show that oxygen vacancies facilitate the adsorption of –C[double bond, length as m-dash]O groups and hinder the adsorption of –C[double bond, length as m-dash]C groups in cinnamaldehyde, which ensures the high selectivity to cinnamyl alcohol. The highly dispersed and electron-rich transition metal hydroxides facilitated the activation of isopropanol to provide active H species under light irradiation and then enhanced the photocatalytic performance. This study demonstrated oxygen vacancy enriched MgAl-LDH supported transition metal hydroxide M(OH)x photocatalysts for efficient selective hydrogenation under visible light irradiation.

Graphical abstract: Oxygen vacancy regulated selective hydrogenation of α,β-unsaturated aldehydes over LDH surface group coordinated transition metal photocatalysts
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