Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO2 for the low-temperature oxidation of CO?
Chemical Communications Pub Date: 2023-05-11 DOI: 10.1039/D3CC01094E
Abstract
Isolated Pd atoms supported on high surface area MnO2, prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O2, 2.6 kPa CO) with results of in situ/operando and ex situ spectroscopic characterization signifying a synergistic role of Pd and MnO2 in facilitating redox turnovers.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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