Aromatic Pummerer reaction for the remote para- or ortho-benzyl nucleophilic functionalization?
Organic Chemistry Frontiers Pub Date: 2018-01-08 DOI: 10.1039/C7QO00970D
Abstract
The classic Pummerer reaction involves an α-substituted sulfide via an elimination/addition of a thionium ion. In this paper, we reported a remote para- or ortho-benzyl nucleophilic functionalization using an aromatic Pummerer process. A plausible mechanism involving a quinone thionium intermediate was proposed to explain this reaction.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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