Anti-Markovnikov additions to N-allylic derivatives involving ammonium–carbenium superelectrophiles??

Chemical Communications Pub Date: 2012-04-16 DOI: 10.1039/C2CC32246C

Abstract

Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium–carbenium superelectrophiles in this original process.

Graphical abstract: Anti-Markovnikov additions to N-allylic derivatives involving ammonium–carbenium superelectrophiles
Recommended Literature