An effective preparation of both 1,3-diketones and nitriles from alkynones with oximes as hydroxide sources?
Organic & Biomolecular Chemistry Pub Date: 2018-09-03 DOI: 10.1039/C8OB01861H
Abstract
An effective phosphine-catalyzed protocol has been established for the syntheses of 1,3-diketones and nitriles from alkynones with oximes as hydroxide surrogates. This method features the use of a phosphine catalyst, compatibility with various functional groups and ambient temperature, which makes this approach very practical. A plausible mechanism was proposed.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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