Aldol reactions mediated by a tetrahedral boronate?
Chemical Communications Pub Date: 2012-11-16 DOI: 10.1039/C2CC37047F
Abstract
The base is a key factor in aldol reactions in organic media, determining the selectivity. Here, we describe a tetrahedral phenylboronate salt as a mild non-nucleophilic base that is able to catalyse the aldol reaction and significantly decrease the formation of undesired elimination products.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4