Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt?
RSC Advances Pub Date: 2021-01-18 DOI: 10.1039/D0RA10739E
Abstract
The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(I) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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