Visible light promoted fluoroalkylation of alkenes and alkynes using 2-bromophenol as a catalyst?
Chemical Communications Pub Date: 2019-09-18 DOI: 10.1039/C9CC06587C
Abstract
We report a new protocol for the fluoroalkylation of alkenes and alkynes by using 2-bromophenol as a catalyst. This reaction can be tailored for different reaction modes by altering the base and solvent, which feature a wide substrate scope and excellent functional group tolerance with high chemo- and regioselectivities. We further propose a mechanism involving an electron donor–acceptor (EDA) complex.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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