The chemistry of organoimido derivatives of polyoxometalates

Dalton Transactions Pub Date: 2012-02-22 DOI: 10.1039/C2DT11948J

Abstract

The chemistry of organoimido derivatives of polyoxometalates (POMs) has received increasing interest. In recent decades, a great development of the synthetic chemistry of organoimido derivatives of POMs using different imido-releasing reagents has taken place, particularly the novel DCC-dehydrating protocol to prepare organoimido derivatives of POMs was developed recently by us and co-workers. Organoimido substituted POMs as valuable building blocks can construct novel nanostructured organic–inorganic hybrid molecular materials in well-developed common organic synthesis methods, such as Pd-catalyzed carbon–carbon coupling and esterification. Therefore, the reactive chemistry of organoimido derivatives of POMs stands for the fascinating future of the chemistry of organoimido derivatives of POMs.

Graphical abstract: The chemistry of organoimido derivatives of polyoxometalates
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