Synthesis of bis(σ-aryl)dirhodium(iii) caprolactamates by oxidative arylation with arylboronic acids??

Chemical Communications Pub Date: 2008-05-14 DOI: 10.1039/B806283H

Abstract

Recently discovered stable bis(σ-phenyl)dirhodium(III) caprolactamate and its substituted derivatives are conveniently prepared in high yields from dirhodium(II) caprolactamate and commercially available arylboronic acids in a copper-catalyzed process.

Graphical abstract: Synthesis of bis(σ-aryl)dirhodium(iii) caprolactamates by oxidative arylation with arylboronic acids
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