Synthesis of benzimidazoles via iridium-catalyzed acceptorless dehydrogenative coupling?
Organic & Biomolecular Chemistry Pub Date: 2015-05-28 DOI: 10.1039/C5OB00904A
Abstract
Iridium-catalyzed acceptorless dehydrogenative coupling of tertiary amines and arylamines has been developed. A number of benzimidazoles were prepared in good yields. An iridium-mediated C–H activation mechanism is suggested. This finding represents a novel strategy for the synthesis of benzimidazoles.
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Journal Name:Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4