Synthesis of a disulfide-bridged bispillar[5]arene and its application in supramolecular polymers?
Polymer Chemistry Pub Date: 2016-02-17 DOI: 10.1039/C6PY00148C
Abstract
A disulfide-bridged bispillar[5]arene was synthesized via efficient oxidation of thiol-pillar[5]arene. The resulting disulfide-bridged bispillar[5]arene was successfully applied in constructing linear supramolecular polymers which were confirmed by concentration-dependent 1H NMR spectroscopy, 2D DOSY and viscosity measurements. Such supramolecular polymers manifested redox responsiveness and were fabricated into water dispersible nanospheres with high fluorescence properties.
![Graphical abstract: Synthesis of a disulfide-bridged bispillar[5]arene and its application in supramolecular polymers](http://scimg.chem960.com/usr/1/C6PY00148C.jpg)
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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