Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Green Chemistry Pub Date: 2011-04-26 DOI: 10.1039/C1GC15076F

Abstract

An expedient, non-metallic green protocol for aerobic oxidation of alcohols was established. 1-Methyl-2-azaadamantane N-oxyl was used as the core catalyst due to its superior chemical stability and catalytic performance. The catalyst can be easily reused through phase separation by taking advantage of its solubility feature, which varies with its oxidation state.

Graphical abstract: Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation
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