Single electron transfer-induced coupling of alkynylzinc reagents with aryl and alkenyl iodides??
Chemical Communications Pub Date: 2016-11-10 DOI: 10.1039/C6CC08038C
Abstract
Alkynylzinc reagents were found to undergo coupling with aryl and alkenyl iodides to give arylalkynes and alkenylalkynes without the aid of transition metals. The coupling reaction proceeds through a single electron transfer mechanism, where a substoichiometric amount of a phosphine works as an indispensable activator.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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