Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator?
Chemical Communications Pub Date: 2018-01-04 DOI: 10.1039/C7CC09036F
Abstract
The 2-electron reduced form of the polyoxometalate silicotungstic acid (H4[SiW12O4]) is shown to be an effective and selective hydrogenation agent for a range of nitroarenes without the need for any co-catalyst. The ease of generation of the active species and its recyclability suggest that a new approach to this important class of chemical conversions is possible.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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