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Reactive MALDI mass spectrometry: application to high mass alkanes and polyethylene?

Chemical Communications Pub Date: 2007-08-21 DOI: 10.1039/B711932A

Abstract

A molecular solid of fullerene (C₆₀) intercalated with cobalt cyclopentadienyl dicarbonyl (CoCp(CO)₂) was shown to be an effective matrix for matrix-assisted laser desorption/ionization mass spectrometry (MALDI) of large alkanes (demonstrated up to C₉₄H₁₉₀) and polyethylenes that otherwise cannot be produced as intact ions in the gas phase.

Graphical abstract: Reactive MALDI mass spectrometry: application to high mass alkanes and polyethylene

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Chemical Communications

Journal Name：Chemical Communications

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