Photocatalytic, site-selective oxidations of carbohydrates?
Chemical Communications Pub Date: 2021-11-01 DOI: 10.1039/D1CC05124E
Abstract
Site-selective oxidations of carbohydrates, employing acridinium photocatalysis and quinuclidine hydrogen atom transfer catalysis, are presented. Protocols have been developed for oxidations of all-equatorial carbohydrates as well as those containing cis-1,2-diols. Site-selectivity reflects the relative rates of hydrogen atom transfer from the carbohydrate C–H bonds, and can be enhanced using a phosphate hydrogen-bonding or boronic acid catalyst.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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