Palladium-catalyzed salt-free double decarboxylative aryl allylation?
Organic & Biomolecular Chemistry Pub Date: 2018-08-15 DOI: 10.1039/C8OB01806E
Abstract
This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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