Palladium catalysed aryl amination reactions in supercritical carbon dioxide
Organic & Biomolecular Chemistry Pub Date: 2005-09-13 DOI: 10.1039/B509345G
Abstract
Palladium catalysed C–N bond formation in supercritical carbon dioxide has been accomplished. Carbamic acid formation is avoided in part through the use of an N-silylamine as the coupling partner. Employing a catalyst system of Pd2dba3
(1 mol%) and 2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl (
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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