Oxidative cross S–H/S–H coupling: selective synthesis of unsymmetrical aryl tert-alkyl disulfanes?
Organic Chemistry Frontiers Pub Date: 2015-03-25 DOI: 10.1039/C5QO00027K
Abstract
Selective oxidative coupling between aryl and tert-alkyl mercaptans was achieved using tert-butyl hydroperoxide (TBHP) as the oxidant and N-iodosuccinimide (NIS) as a catalyst. This protocol may provide an efficient process to synthesize unsymmetrical aryl tert-alkyl disulfanes.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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