Organocatalyzed cascade reactions of carbohydrates – a direct access to C-glycosides?
Chemical Communications Pub Date: 2013-11-13 DOI: 10.1039/C3CC48120D
Abstract
An organocatalyzed transformation to elongate unprotected carbohydrates is described. This operationally simple methodology is based on a Knoevenagel–oxa-Michael cascade. This reaction is catalyzed by proline and DBU. Products were obtained with exceptional high degrees of stereoselectivity.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4