An enzymatic route to a benzocarbazole framework using bacterial CotA laccase?
Green Chemistry Pub Date: 2015-01-19 DOI: 10.1039/C4GC02511C
Abstract
The CotA laccase-catalysed oxidation of the meta,para-disubstituted arylamine 2,4-diaminophenyldiamine delivers, under mild reaction conditions, a benzocarbazole derivative (1) (74% yield), a key structural motif of a diverse range of applications. This work extends the scope of aromatic frameworks obtained using these enzymes and represents a new efficient and clean method to construct in one step C–C and C–N bonds.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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