Natural product syntheses via carbonylative cyclizations
Natural Product Reports Pub Date: 2018-06-20 DOI: 10.1039/C8NP00033F
Abstract
Covering: 2000–2018
In this review, we highlight recent examples of natural product total syntheses employing transition metal-mediated/catalyzed carbonylative cyclization strategies to build key ring systems. It mainly covers carbonylative cyclizations for the construction of O-heterocycles, N-heterocycles and carbocycles including cyclic ketones and phenols. The reaction types include carbonylation of epoxide to β-lactones, carbonylative (macro)lactonization/lactamization, the Semmelhack reaction, tandem hydroformylation–cyclization, the Pauson–Khand reaction, carbonylative C–H activation cyclization, the Stille/Suzuki carbonylation, [n + m + 1] carbonylative cycloaddition, the D?tz annulation, and others.
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Journal Name：Natural Product Reports
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CAS no.: 89640-58-4
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