Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination?
Chemical Communications Pub Date: 2020-09-16 DOI: 10.1039/D0CC05424K
Abstract
First Ln(II) ring-expanded NHC complexes (er-NHC)Ln[N(SiMe3)2]2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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