Ligand-directed assembly engineering of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime?

Dalton Transactions Pub Date: 2019-06-04 DOI: 10.1039/C9DT02032B

Abstract

Through ligand-directed assembly of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime, eight titanium-oxo molecular clusters with a sandwich or square planar type structures were successfully constructed, including the first success on the combination of porphyrin and titanium-oxo clusters.

Graphical abstract: Ligand-directed assembly engineering of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime
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