Hypervalent iodine reagent-mediated reactions involving rearrangement processes
Chemical Communications Pub Date: 2020-10-01 DOI: 10.1039/D0CC05354F
Abstract
Hypervalent iodine reagents have been extensively employed in various types of oxidative organic reactions including oxidative coupling/cyclization, bifunctionalization of olefins and cyclopropane, C–H functionalization, and oxidative rearrangement reactions. In this review, the developments of the exclusive hypervalent iodine-mediated reactions involving oxidative rearrangement processes, including [1,2]-migration, Hofmann rearrangement, Beckmann rearrangement, ring contraction, ring expansion, [3,3]-sigmatropic/iodonium-Claisen rearrangement and some miscellaneous rearrangements, have been summarized.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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