Hydrogen bonding mediated orthogonal and reversible self-assembly of porphyrin sensitizers onto TiO2 nanoparticles?
Chemical Communications Pub Date: 2016-06-17 DOI: 10.1039/C6CC03452G
Abstract
We report on the orthogonal, highly directional and reversible self-assembly of porphyrins onto TiO2 nanoparticles by means of hydrogen bonding interactions. Unifying the stable covalent surface attachment of tailored, synthesized Hamilton receptors with the advantages of a non-covalent supramolecular immobilization of porphyrin cyanurates resulted in a redox- and photo-active nanohybrid. The latter was successfully implemented into a new type of supramolecular dye-sensitized solar cells.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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