Highly atom-economical, catalyst-free, and solvent-free phosphorylation of chalcogenides??
Organic & Biomolecular Chemistry Pub Date: 2019-10-25 DOI: 10.1039/C9OB01921A
Abstract
Silica gel promoted, catalyst-free and solvent-free S–P, Se–P and Te–P bond formations are described. A variety of disulfides coupled with diarylphosphine oxides provide the corresponding phosphinothioates in excellent yields. For the first time, diselenides and ditellurides reacted with dialkyl phosphites under catalyst-free conditions to provide the corresponding phosphoroselenoates and phosphorotelluroates, respectively, in good to excellent yields.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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