Gas-phase synthesis and reactivity of Cu+–benzyne complexes?
Chemical Communications Pub Date: 2014-08-07 DOI: 10.1039/C4CC04168B
Abstract
Cu+–benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products were identified by comparing their MSn data with authentic compounds obtained from another generation route.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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