Enantioselective domino reaction of CO2, amines and allyl chlorides under iridium catalysis: formation of allyl carbamates?
Chemical Communications Pub Date: 2014-03-07 DOI: 10.1039/C4CC00413B
Abstract
The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with up to excellent regioselectivity (99/1) and 94% ee. This is the first example of the synthesis of chiral allyl carbamates through catalytic domino reactions using CO2.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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