DMAP and PivOH-promoted amination/allenization reaction?
Chemical Communications Pub Date: 2020-07-08 DOI: 10.1039/D0CC03749D
Abstract
This report described the first DMAP and PivOH-promoted ortho-C–H amination and ipso-allenization reaction of iodobenzenes realized by Pd/norbornene cooperative catalysis. Based on control experiments and DFT calculations, we speculated that the three ligands have different functions and mechanism paths in the reaction.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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