Copper(ii)-promoted direct conversion of methylarenes into aromatic oximes?
Organic & Biomolecular Chemistry Pub Date: 2015-06-09 DOI: 10.1039/C5OB00923E
Abstract
A simple and efficient catalytic system for direct conversion of methylarenes into aromatic oximes has been developed, with Cu(OAc)2 as catalyst, NHPI (N-Hydroxyphthalimide) as additive, TBN (tert-butyl nitrite) as both the nitrogen source and the oxidant. This process proceeds under mild conditions, tolerates a wide range of substrates, affording the targeted aromatic oximes in 63–86% yields.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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