γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes?

Chemical Communications Pub Date: 2012-11-01 DOI: 10.1039/C2CC36199J

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90–95% ee).

Graphical abstract: γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes
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