Visible-light-promoted N-centered radical generation for remote heteroaryl migration?

Organic & Biomolecular Chemistry Pub Date: 2020-09-09 DOI: 10.1039/D0OB01594F

Abstract

Herein, an efficient visible-light-mediated N–H heteroarylation via remote heteroaryl ipso-migration has been accomplished. Moderate to good yields were obtained with good functional group tolerance. Moreover, a simple and readily available organic photoredox catalyst was employed, avoiding the use of complex and costly noble metal compounds.

Graphical abstract: Visible-light-promoted N-centered radical generation for remote heteroaryl migration
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