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Triterpenoid total synthesis. Synthesis and absolute configuration of mispyric acid?

Organic & Biomolecular Chemistry Pub Date: 2004-07-14 DOI: 10.1039/B406820C

Abstract

The first synthesis of mispyric acid (1), an inhibitor of DNA polymerase β with a novel triterpene skeleton, was achieved by starting from isoprene (2), geraniol (6) and 1,5-dimethoxy-1,4-cyclohexadiene (14). The absolute configuration of the naturally occurring 1 was determined as 2S,4S.

Graphical abstract: Triterpenoid total synthesis. Synthesis and absolute configuration of mispyric acid

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Organic & Biomolecular Chemistry

Journal Name：Organic & Biomolecular Chemistry

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