Visible-light-mediated difunctionalization of vinylcyclopropanes for the synthesis of 1-sulfonylmethyl-3,4-dihydronaphthalenes?
Organic & Biomolecular Chemistry Pub Date: 2019-07-30 DOI: 10.1039/C9OB01321K
Abstract
An efficient method for visible-light-mediated sulfonylation/arylation of the C–C σ-bond in vinylcyclopropanes with sulfonyl chlorides to synthesize 1-sulfonylmethyl-substituted 3,4-dihydronaphalenes has been developed. A radical-type pathway has been proved in this transformation. This difunctionalization procedure shows a series of advantages, such as the use of commercially and easily available sulfonyl chlorides, mild conditions, and eco-friendly energy.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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