Well-defined transition metal hydrides in catalytic isomerizations

Chemical Communications Pub Date: 2014-06-05 DOI: 10.1039/C4CC02399D

Abstract

This Feature Article intends to provide an overview of a variety of catalytic isomerization reactions that have been performed using well-defined transition metal hydride precatalysts. A particular emphasis is placed on the underlying mechanistic features of the transformations discussed. These have been categorized depending upon the nature of the substrate and in most cases discussed following a chronological order.

Graphical abstract: Well-defined transition metal hydrides in catalytic isomerizations
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