Visible light-mediated oxidative C(sp3)–H phosphonylation for α-aminophosphonates under oxidant-free conditions?
Chemical Communications Pub Date: 2018-01-16 DOI: 10.1039/C7CC09624K
Abstract
An external oxidant-free synthesis of α-aminophosphonates by synergistically combining photocatalysis and proton-reduction catalysis is developed herein. The gram-scale experiment demonstrates the potential utility of this protocol. This study may have important implications for the functionalization of oxidant-sensitive C(sp3)–H bonds.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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