Vinylogous Nicholas reactions in the synthesis of bi- and tricyclic cycloheptynedicobalt complexes?
Organic & Biomolecular Chemistry Pub Date: 2015-09-07 DOI: 10.1039/C5OB01684C
Abstract
The Lewis acid mediated intramolecular Nicholas reactions of allylic acetate enyne-Co2(CO)6 complexes afford cycloheptenyne-Co2(CO)6 complexes in three manifestations. Electron rich aryl substituted alkyne complexes give tricyclic 6,7,x-benzocycloheptenyne complexes, with x = 5, 6, or 7. Allylsilane substituted complexes afford exo methylene bicyclic x,7-cycloheptenyne complexes (x = 6,7). The allyl acetate function may also be replaced by a benzylic acetate, to afford dibenzocycloheptyne-Co2(CO)6 complexes. Following reductive complexation, the methodology may be applied to the synthesis of the icetexane diterpene carbon framework.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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