Two solid state phases of 1-bromo-2,4,6-trifluorobenzene, crystallised under non-ambient conditions?

CrystEngComm Pub Date: 2010-07-12 DOI: 10.1039/C001539N

Abstract

PhBrF3, a liquid under ambient conditions, has been crystallised via two different methods, resulting in the formation of non-identical solid-state phases with very similar packing efficiencies but markedly different packing motifs, both of which appear to be directed by classically weak intermolecular halogen–halogen interactions.

Graphical abstract: Two solid state phases of 1-bromo-2,4,6-trifluorobenzene, crystallised under non-ambient conditions
Recommended Literature