UV light-mediated difunctionalization of alkenes with CF3SO2Na: synthesis of trifluoromethyl phenanthrene and anthrone derivatives?
Organic & Biomolecular Chemistry Pub Date: 2016-05-11 DOI: 10.1039/C6OB00912C
Abstract
A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp3–CF3 and C–C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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