A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface?

Chemical Communications Pub Date: 2018-07-16 DOI: 10.1039/C8CC03484B

Abstract

The title MOF features a potential uninodal zeolite net, uks, which has never been found for real zeolites or zeolite-like MOFs. This rare structure exhibits specific anion binding of N3? over SCN? in water, which reverses the Hofmeister series.

Graphical abstract: A zeolite-like MOF based on a heterotritopic linker of imidazolyl, carboxyl and pyridine with a long-sought uks net on Schwarz's D-surface
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